According to Today in History today is the day in 1842 that anesthesia was used during an operation for the first time. (Kinda makes you glad to be living in this century, huh?)
Here is a site with links to various anesthesia museums and an anesthesia history calendar by Thomas J. Evans, CRNA, MS.
Anesthesia History Page
Also, take a look at How Anesthesia Works on the HowStuffWorks site.
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